Onset of electroconvection of homeotropically aligned nematic liquid crystals.

We present experimental measurements near the onset of electroconvection (EC) of homeotropically aligned nematic liquid crystals Phase 5A and MBBA. A voltage of amplitude square root 2V0 and frequency f was applied. With increasing V0, EC occurred after the bend Freedericksz transition. We found supercritical bifurcations to EC that were either stationary bifurcations or Hopf bifurcations to traveling convection rolls, depending on the sample conductances. Results for the onset voltages Vc, the critical wave numbers kc, the obliqueness angles thetac, and the traveling-wave (Hopf) frequencies at onset omegac over a range of sample conductances and driving frequencies are presented and compared, to the extent possible, with theoretical predictions. For the most part good agreement was found. However, the experiment revealed some unusual results for the orientations of the convection rolls relative to the direction selected by the Freedericksz domain.